A valence bond description of the bromine halogen bond

The Halogen Bond

The halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity. In this fairly extensive review, after a brief history of the interaction, we will provide the reader with a snapshot of where the research on the halogen bond is n...

Bosonic Resonating-Valence-Bond Description of a Doped Antiferromagnet

We propose a theory for a doped antiferromagnet based on the bosonic resonating-valence-bond (RVB) description incorporating the phase string effect. Both antiferromagnetic and superconducting phase transitions occur naturally inside such a bosonic RVB phase. Two distinct metallic regions— underdoping and optimum doping—are also found to be a logical consequence; their unique features explain t...

Base-promoted aryl-bromine bond cleavage with cobalt(II) porphyrins via a halogen atom transfer mechanism.

Aryl-bromine bonds are successfully cleaved by cobalt(II) porphyrins in basic media to give Co(por)Ar (por = porphyrin) in good yields. Mechanistic studies suggested that the aryl-bromine bond is cleaved through a halogen atom transfer mechanism, which is different from the aryl-halogen bond cleavage mechanism with other group 9 metalloporphyrins.

The Valence Bond Glass phase

We show that a new glassy phase can emerge in presence of strong magnetic frustration and quantum fluctuations. It is a Valence Bond Glass. We study its properties solving the Hubbard-Heisenberg model on a Bethe lattice within the large N limit introduced by Affleck and Marston. We work out the phase diagram that contains Fermi liquid, dimer and valence bond glass phases. This new glassy phase ...

Heisenberg Antiferromagnet on Square-Kagomé Lattice: Resonating Valence Bond Description